Richard Lawrence Poppe, Age 77452 County Road 308, Dreyer, TX 77984

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452 County Road 308, Shiner, TX 77984

Richwood, TX

Katy, TX

Yoakum, TX

Franklin, TX

Midland, TX

Odessa, TX

Pecos, TX

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Publications & IP owners

Us Patents

Method For Making Acrolein And Catalyst Therefor

US Patent:
4129600, Dec 12, 1978
Filed:
Mar 18, 1977
Appl. No.:
5/778907
Inventors:
David L. Childress - Angleton TX
William V. Hayes - Clute TX
Richard L. Poppe - Clute TX
Assignee:
The Dow Chemical Company - Midland MI
International Classification:
C07C 4720
C07C 4722
US Classification:
260604R
Abstract:
A method of preparing acrolein and methacrolein by oxidation of propylene and isobutylene over a new improved catalyst providing conversions and yields, each greater than 90% in a single-pass reactor. The improved catalyst contains within certain prescribed proportions the oxides of cobalt, iron, bismuth, molybdenum, potassium, and optionally silicon. The metals have atomic ratios of Co. sub. 3-10 Fe. sub. 5-3. 0 Bi. sub. 5-3. 0 Mo. sub. 15 K. sub. 01-0. 5 Si. sub. 5-3. 0 and are present in the form of oxides as pellets, spheres, or on a support. With a recycle system, a conversion of the olefin greater than 99% and yield to the aldehyde of greater than 95% are possible.

Catalyst For Making Acrolein

US Patent:
4049577, Sep 20, 1977
Filed:
Dec 15, 1975
Appl. No.:
5/640616
Inventors:
David L. Childress - Angleton TX
William V. Hayes - Clute TX
Richard L. Poppe - Clute TX
Assignee:
The Dow Chemical Company - Midland MI
International Classification:
B01J 2104
B01J 2378
B01J 2384
B01J 2720
US Classification:
252443
Abstract:
A method of preparing acrolein and methacrolein by oxidation of propylene and isobutylene over a new improved catalyst providing conversions and yields, each greater than 90% in a single-pass reactor. The improved catalyst contains within certain prescribed proportions the oxides of cobalt, iron, bismuth, molybdenum, potassium, and optionally silicon. The metals have atomic ratios of Co. sub. 3-10 Fe. sub. 5-3. 0 Bi. sub. 5-3. 0 Mo. sub. 15 K. sub. 01-0. 5 Si. sub. 5-3. 0 and are present in the form of oxides as pellets, spheres, or on a support. With a recycle system, a conversion of the olefin greater than 99% and yield to the aldehyde of greater than 95% are possible.

Method For Making Acrylic Acid From Acrolein

US Patent:
4350830, Sep 21, 1982
Filed:
Oct 17, 1979
Appl. No.:
6/085568
Inventors:
David L. Childress - Angleton TX
William V. Hayes - Clute TX
Richard L. Poppe - Clute TX
Assignee:
The Dow Chemical Co. - Midland MI
International Classification:
C07C 5125
C07C 57055
US Classification:
562535
Abstract:
A method for preparing acrylic acid by oxidation of acrolein over a new and improved catalyst providing conversions of acrolein of greater than 99% with yields of acrylic acid in excess of 95%. The catalyst consists essentially of the oxides of molybdenum, vanadium, chromium, copper and titanium and optionally silicon on an inert carrier. Catalysts useful in the process contain the elements previously mentioned in the atomic ratios of Mo. sub. 15 V. sub. 5-10 Cu. sub. 2-5 Cr. sub. 2-2 Ti. sub. 1-3.

Acrolein Oxidation Catalyst

US Patent:
4035262, Jul 12, 1977
Filed:
Apr 19, 1976
Appl. No.:
5/678274
Inventors:
David L. Childress - Angleton TX
William V. Hayes - Clute TX
Richard L. Poppe - Clute TX
Assignee:
The Dow Chemical Company - Midland MI
International Classification:
B01J 2108
B01J 2322
B01J 2326
B01J 2328
US Classification:
252456
Abstract:
A method of preparing acrylic acid by oxidation of acrolein over a new and improved catalyst providing conversions of acrolein of greater than 99% with yields of acrylic acid in excess of 95%. The catalyst consists essentially of the oxides of molybdenum, vanadium, chromium and copper and at least one of tantalum and niobium and optionally silicon on an inert carrier. Catalysts useful in the process contain the elements previously mentioned in the atomic ratios of Mo. sub. 15 V. sub. 5-10 Cu. sub. 2-5 Cr. sub. 2-2 M. sub. 1-3 where M is tantalum, niobium or mixtures thereof.

Catalyst For Making Acrylic Acid From Acrolein Or Propylene

US Patent:
4208306, Jun 17, 1980
Filed:
Oct 26, 1978
Appl. No.:
5/955045
Inventors:
David L. Childress - Angleton TX
William V. Hayes - Clute TX
Richard L. Poppe - Clute TX
Assignee:
The Dow Chemical Company - Midland MI
International Classification:
B01J 2106
B01J 2108
US Classification:
252456
Abstract:
A method for preparing acrylic acid by oxidation of acrolein over a new and improved catalyst providing conversions of acrolein of greater than 99% with yields of acrylic acid in excess of 95%. The catalyst consists essentially of the oxides of molybdenum, vanadium, chromium, copper and titanium and optionally silicon on an inert carrier. Catalysts useful in the process contain the elements previously mentioned in the atomic ratios of Mo. sub. 15 V. sub. 5-10 Cu. sub. 2-5 Cr. sub. 2-2 Ti. sub. 1-3.

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