John J Sibilia, Age 61Wake Forest, NC

4696857, Sep 29, 1987

Dec 13, 1985

6/808807

John P. Sibilia - Livingston NJ
Abraham M. Kotliar - Westfield NJ
Narasimhaiah S. Murthy - Belle Mead NJ
William Sacks - Gillette NJ

Allied Corporation - Morris Township, Morris County NJ

B32B 516
B29B 1700

428323

The permeation resistance to gases and vapors of polymeric articles including thin walled articles such as films and bottles can be increased by annealing the film. A preferred embodiment is one where the preferred polymer is polycaprolactam or high density polyethylene. There is from 1 to 50 percent of a platelet filler having an average equivalent diameter of from 1 to 8 micrometers, a maximum equivalent diameter of about 25 micrometers, and an average thickness of less than 0. 5 micrometers.

4876127, Oct 24, 1989

Nov 9, 1988

7/269030

Yash P. Khanna - Cedar Knolls NJ
Himangshu R. Bhattacharjee - Randolph NJ
Rakesh Kumar - Budd Lake NJ
Jon I. Williams - Montclair NJ
John P. Sibilia - Livingston NJ

Allied-Signal Inc. - Morris Township, Morris County NJ

B27N 502

428 357

This invention relates to a process for blow molding polyamide compositions where the molten polyamide includes an effective amount of one or more aryl phosphoryl azide compounds.

4886689, Dec 12, 1989

May 19, 1988

7/196819

Abraham M. Kotliar - Westfield NJ
William Sacks - Gillette NJ
John P. Sibilia - Livingston NJ
Rakesh Kumar - Parsippany NJ

Ausimont, U.S.A., Inc. - Morristown NJ

B27N 502
B29C 4706

428 357

A novel adhesive is described, consisting of a matrix-matrix polyblend of polymer components useful in an adhesive tie layer to bond incompatible polymer layers. The adhesives are a blend of the components making up the incompatible polymer layers themselves, or polymers substantially similar to these, and are melt processed to produce a matrix-matrix morphology with mechanical interlocking of the polymer components that is maintained upon cooling. Additives may be provided in one or both adhesive components to improve the cohesive strength of the adhesive formed by the mechanical interlocking.

4528235, Jul 9, 1985

Aug 5, 1982

6/405225

William Sacks - Gillette NJ
John P. Sibilia - Livingston NJ
Abraham M. Kotliar - Westfield NJ
Harold D. Oltmann - Baton Rouge LA
Shu P. Chen - Baton Rouge LA

Allied Corporation - Morris Township, Morris County NJ

B32B 516
B32B 2708

428220

Thin polymer films containing small sized platelet type filler. The polymer has a melt index of from 0. 01 to 10 grams per 10 minutes at 190. degree. C. to 250. degree. C. as measured on ASTM Test No. D-1238 at a load of 1000 to 2160 grams. The preferred polymer is polycaprolactam or high density polyethylene. There is from 10 to 50 percent of a platelet filler having an average equivalent diameter of from 1 to 8 micrometers, a maximum equivalent diameter of about 25 micrometers, and an average thickness of less than 0. 5 micrometers. The preferred filler is talc. The film is from 10 to 100 micrometers thick and can be a single ply or a laminate.

5496918, Mar 5, 1996

Oct 13, 1994

8/322976

Yash P. Khanna - Cedar Knolls NJ
Kevin R. Slusarz - Greenwich CT
Mina K. Gabriel - Whitehouse Sta NJ
Annemarie C. Reimschuessel - Morristown NJ
John P. Sibilia - Livingston NJ

AlliedSignal Inc. - Morris Township NJ

C08G 6946

528480

This invention relates to a process of forming a polyamide composition having increased crystallization rate which comprises the steps of reducing the oligomeric polyamide content of said composition to less than 8% by weight of the composition, preferably with prior melt shearing, use of 1-2% nucleating filler e. g. talc and a mold release agent.

5032656, Jul 16, 1991

Nov 21, 1990

7/616487

Frank Mares - Whippany NJ
Bryce C. Oxenrider - Florham Park NJ
David J. Long - Amherst NY
John P. Sibilia - Livingston NJ

Allied-Signal Inc. - Morris Township, Morris County NJ

C08F 1418

526255

The present invention is directed to a copolymer of a fluoromonomer having the formula R. sub. 1 R. sub. 2 C=CR. sub. 3 F wherein R. sub. 1, R. sub. 2 and R. sub. 3 are selected from H and F, and R. sub. 3 may be Cl when R. sub. 1 and R. sub. 2 are F; and a vinyl monomer having the formula H. sub. 2 C=CHR. sub. x, wherein R. sub. x is a radical having the formula --O. sub. 2 CR. sub. y, wherein R. sub. y is a radical selected from CH. sub. 3 and C. sub. 2 H. sub. 5. The resulting copolymer comprises fluorinated units having the formula (R. sub. 1 R. sub. 2 C-CR. sub. 3 F) wherein R. sub. 1, R. sub. 2 and R. sub. 3 are selected from H and F, and R. sub. 3 may be Cl when R. sub. 1 and R. sub. 2 are F, and corresponding amounts of vinyl units having the formula (H. sub. 2 C-CHR. sub. x), wherein R. sub.

4618528, Oct 21, 1986

Apr 15, 1985

6/709264

William Sacks - Gillette NJ
John P. Sibilia - Livingston NJ
Abraham M. Kotliar - Westfield NJ
Harold D. Oltmann - Baton Rouge LA
Shu P. Chen - Baton Rouge LA

Allied Corporation - Morris Township, Morris County NJ

B32B 702
B32B 516
B32B 2734

428216

Thin polymer films containing small sized platelet type filler. The polymer has a melt index of from 0. 01 to 10 grams per 10 minutes at 190. degree. C. to 250. degree. C. as measured on ASTM Test No. D-1238 at a load of 1000 to 2160 grams. The preferred polymer is polycaprolactam or high density polyethylene. There is from 10 to 50 percent of a platelet filler having an average equivalent diameter of from 1 to 8 micrometers, a maximum equivalent diameter of about 25 micrometers, and an average thickness of less than 0. 5 micrometers. The preferred filler is talc. The film is from 10 to 100 micrometers thick and can be a single ply or a laminate.

5310775, May 10, 1994

Jul 20, 1992

7/916552

John P. Sibilia - Livingston NJ
Yash P. Khanna - Morris NJ
Anthony J. Signorelli - Succasunna NJ
Dean A. Roberts - Sparta NJ

AlliedSignal Inc. - Morristown NJ

C08J 320
C08K 504
C08K 509
C08L 2718

524398

This invention relates to a composition comprising (a) at least one polymer selected from the group consisting of poly(chlorotrifluoroethylene) and copolymers of chlorotrifluoroethylene and one or more ethylenic comonomers; wherein said copolymers comprise at least about 50% by weight of chlorotrifluoroethylene and (b) effective amount of one or more nucleating agents selected from the group of compounds consisting of silver octonate, calcium carbonate, potassium benzoate, talc and lays bentonite, montmorillonite, hectorite and derivatives thereof.